Comparison of two alluvial aquifers shows the probable role of river sediments on the release of arsenic in the groundwater of district Vehari,Punjab, Pakistan

The study was done to assess the effect of the river Sutlej on arsenic (As) contamination. Sampling was done from the alluvial plain with increasing distance from the river Sutlej in district Vehari and compared with the study done in the proximity of River Sutlej. Sixty (60) groundwater samples mostly from shallow depths were collected and analyzed for As concentrations. Multivariate statistical tools (PCA and CA), saturation index, piper plots and Gibbs diagrams were used to detect evidence about the interrelationship and sources of As and other water quality variables responsible for groundwater contamination. Results revealed that As concentration ranged from below detection limit to 156 µg/L indicating that 50% samples exceeding the WHO guidelines (10 µg/L) and 17% exceeding the Pakistan National Environmental Quality Standards (NEQS) limits (50 µg/L) Sutlej. The piper plot revealed that water chemistry of the study area was Ca–HCO₃^?, Ca–Mg–Cl, type. Correlations between As and HCO₃^? (r²?=?0.433) was positive, while negative correlations were observed between As–Mn²⁺ and As–Fe²⁺ (r²?=???0.102), (r²?=?0.107) respectively. Geochemical signatures of the groundwater in the study area showed that the As could be released by oxidative dissolution to some extent and elevated evaporation in the arid environment of the study area under the stimulus of alkaline water and high pH (range 7.1–8.4). Although the concentrations are exceeding the WHO limit in 50% of the water samples but, are less than the previous study done in Mailsi near River Sutlej. Further, the concentrations decreased as the distance from the River increased which shows the probable role of sediments deposited by the River Sutlej.     

Assessment of trace metals contamination in stream sediments and soils in Abuja leather mining,southwestern Nigeria

This study is aimed at determining the level of environmental degradation as well as the concentration of trace elements in soil and stream sediments in order to evaluate the environmental impact of the mining operation. Twenty-five (25) soils and ten (10) stream sediment samples were collected from the study area. The physicochemical parameters were determined using appropriate instrumentation with the aid of a digital pH meter (Milwaukee meter) to measure the pH and electrical conductivity, total dissolved solids, moisture content and loss on ignition of the soil and stream sediment samples. The pH of the soil sample ranged from (6.10 to 7.19); Electrical conductivity ranged from (21.3 to 279.4 µS/cm), moisture content varied from (0.60% to 7.20%), and the LOI ranged from (2.03% to 18.62%). The results of the analysis showed that the concentrations of the trace elements in the soils and stream sediment samples were slightly higher than the background values. Plots of the trace elements in stream sediment samples show moderate, consistent decrease downstream except at points where there was mine water discharge into the main river. The pollution levels of heavy metals were examined in stream sediment and soil samples using different assessable indices, such as the enrichment factor, which showed significant-moderate enrichment for Cr, Th, Nb, Zn, Pb, Y and Zr and the geo-accumulation index, which showed practically moderate contamination with Cr, Ni and Sr based on regional background reference values. Geo-accumulation index and contamination index for soils and stream sediment revealed uncontaminated to moderate contamination. Likewise, elements with moderate contamination were Cr, Ni and Sr. The Pearson correlation showed that there were significant positive associations among selected metals in soil and stream sediment samples.     

A laboratory study of the turbulent ekman layer

Abstract

Comparing characteristics of a turbulent Ekman boundary layer in a rotating apparatus with atmospheric observations and theories, we find that the similarity relations derived by Kazanski and Monin, and others, scale both laboratory and field data quite well, especially considering that the Coriolis parameter is larger by a factor of 10⁵ in the experiment than it is in the atmosphere. Eddy viscosity models and Deardorff's numerical model predict the properties of both with varying degrees of success. High frequency spectra of velocity fluctuations scale with the Kolmogoroff length and time scales. Both magnitude and direction of the surface shear stress were measured directly, with a heated film stress gauge.     

Biosorption of methylene blue from aqueous solutions by Typha angustata phytomass

The objective of this study was to investigate the biosorption of an azo dye (Methylene blue) by a wetland phytomass (Typha angustata) under post-phytoremediation scenario. Thus, the phytomass was used without any chemical modification. The batch adsorption experiments were conducted to evaluate the effects of contact time and temperatures (25–45 °C) on the adsorption of methylene blue (MB) from aqueous solution by cattail phytomass (CP). More than 80 % of MB dye was removed from the aqueous solution within first 10 min of the experiment. Langmuir isotherm was modeled to describe the monolayer adsorption of MB dye (R ² = 0.995) with the maximum adsorption capacity of 8.1 mg/g at 25 °C. Pseudo-second-order kinetic model adequately described the kinetics of absorption process (R ² = 0.999). The adsorption of MB on the cattail phytomass was a spontaneous and endothermic process that was governed by chemisorption. Hence, CP could be applied as a potential low cost biosorbent to treat dyeing wastewater.     

Thermal and shock history of Almahata Sitta meteorite inferred from structure refinement of pyroxene and Mössbauer spectroscopy of Fe-Ni metal

The crystal structures of orthopyroxene (En_86.3Fs_8.6Wo_5.1, space group Pbca) and pigeonite (En_81.7Fs_8.8Wo_9.5, space group P2₁/c) from the Almahata Sitta ureilite (fragment#051) have been refined to R1 indices of 3.10% and 2.53%, respectively, using single-crystal X-ray diffraction data. The unit formulas were calculated from electron microprobe analysis, and the occupancies at the M1 and M2 sites were refined for both pyroxenes from the single-crystal diffraction data. The results indicate a rather disordered intracrystalline Fe²⁺-Mg cation distribution over the M1 and M2 sites, with a closure temperature of 726(±55)°C for orthopyroxene and 704(±110)°C for pigeonite, suggesting fast cooling of these pyroxenes. The Mössbauer spectrum of the Fe-Ni metal particles of Almahata Sitta ureilite (fragment#051) is dominated by two overlapping magnetic sextets that are assigned to Fe atoms in Si-bearing kamacite, and arise from two different nearest-neighbor configurations of Fe* (=Fe+Ni) and Si atoms in the bcc structure of kamacite; (8F*, 0Si) and (7Fe*, 1Si). In addition, the spectrum shows weak absorption peaks that are attributed to the presence of small amounts of cohenite [(Fe,Ni)₃C], schreibersite [(Fe,Ni)₃P], and an Fe-oxide/hydroxide phase. The fast cooling of pyroxene to the closure temperature (after equilibration at ~1200°C) and the incorporation of Si in kamacite can be interpreted as due to a shock event that took place on the meteorite parent body, consistent with the proposed formation history of ureilites parent body where a fast cooling has occurred at a later stage of its formation.     

Estimation of concentration and exposure doses due to radon by using CR-39 plastic track detectors in the residences of Sudhnuti, Azad Kashmir, Pakistan

This paper presents the results of indoor radon concentration measurements in 120 dwellings of district Sudhnuti of Azad Kashmir. Measurements were taken with CR-39 passive alpha track detector. CR-39 based box type radon detectors were installed in a bedroom and living rooms of each house. The detectors were retrieved after exposing to indoor radon for period of 6 months and then etched in 6 M NaOH at 80°C for 16 h, the observed track densities were converted in to the indoor radon concentration. Indoor radon concentration varied from 20 ± 12 to 170 ± 4 Bq m⁻³ for the houses of the district Sudhnuti. Arithmetic mean (AM), geometric mean (GM) and geometric standard deviations (GSD) were found to be 82 ± 6, 77 ± 6 and 1.51, respectively. The minimum value of weighted average radon concentration was recorded in one of the house of Mang town, whereas the maximum value was found in the Pattan Sher Khan region. Doses due to indoor radon exposure vary from 0.50 ± 0.31 to 4.28 ± 0.11 mSv year⁻¹ AM, GM and GSD. of mean effective doses were found to be 2.06 ± 0.13, 1.95 ± 0.18 and 1.51, respectively. According to the recommendations made by the Health Protection Agency, UK (200 Bq m⁻³) all the houses surveyed are within the safe limits.     

Facies Analysis, Sequence Stratigraphy and Diagenetic Studies of the Jurassic Carbonates of the Kohat Basin, Northwest Pakistan: Reservoir Implications

The present study deals with the depositional facies, diagenetic processes and sequence stratigraphy of the shallow marine carbonates of the Samana Suk Formation, Kohat Basin, in order to elucidate its reservoir quality. The Samana Suk Formation consists of thin to thick-bedded, oolitic, bioclastic, dolomitic and fractured limestone. Based on the integration of outcrop, petrographic and biofacies analyses, the unit is thought to have been deposited on a gentle homoclinal ramp in peritidal, lagoonal and carbonate shoal settings. Frequent variations in microfacies based sea-level curve have revealed seven Transgressive Systems Tracts (TSTs) and six Regressive Systems Tracts (RSTs). The unit has undergone various stages of diagenetic processes, including mechanical and chemical compaction, cementation, micritization, dissolution and dolomitization. The petrographic analyses show the evolution of porosity in various depositional and diagenetic phases. The fenestral porosity was mainly developed in peritidal carbonates during deposition, while the burial dissolution and diagenetic dolomitization have greatly enhanced the reservoir potential of the rock unit, as is further confirmed by the plug porosity and permeability analyses. The porosities and permeabilities were higher in shoal facies deposited in TSTs, as compared to lagoonal and peritidal facies, except for the dolomite in mudstone, deposited during RSTs. Hence good, moderate and poor reservoir potential is suggested for shoal, lagoonal and peritidal facies, respectively.     

Felsic dykes in the Neoproterozoic Nagar Parkar Igneous Complex,SE Sindh,Pakistan: geochemistry and tectonic settings

The Nagar Parkar Igneous Complex consists of Neoproterozoic igneous and metamorphic rocks dissected by mafic, felsic, and rhyolitic dykes. The latter can be classified broadly into porphyritic felsic dykes intruding gray and pink granites at Nagar Parkar and the surrounding areas, and the orthophyric felsic dykes intruding amphibolites, deformed pink granites, and the alkaline mafic dykes in the Dhedvero area, north of Nagar Parkar. The porphyritic felsic dykes are composed of perthites, quartz, and albitic plagioclase whereas the orthopheric felsic dykes contain K-feldspar (dominant), plagioclase, and minor quartz. Geochemically, the porphyritic and orthophyric felsic dykes are subalkaline and alkaline demonstrating post-orogenic A2- and OIB-A1-type characteristic on Nb–Y–Ce and Nb–Y–3Ga ternary plots, respectively. One orthophyric felsic dyke contains normative acmite and sodium metasilicate. This study suggests two distinct tectonic regimes for the origin of the felsic dykes of the area. The porphyritic felsic dykes show similarities with the ~800–700 Ma granites of the area, the rhyolite dykes of the Mount Abu, western Rajasthan in India, and the granites of the Seychelles microcontinent. The orthophyric felsic dykes show chemical resemblance with the Tavidar volcanic suite of western Rajasthan and the Silhouette and North islands of the Seychelles microcontinent. This study confirms spatial and temporal links among the Rodinian fragments exposed in the Nagar Parkar area of Pakistan, western Rajasthan of India, and the Seychelles microcontinent.